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A CASE OF SOLID-STATE ISOMERISM FOR A RHODIUM CARBONYL CLUSTER ANION. SYNTHESIS, CHARACTERIZATION IN SOLUTION AND X-RAY CRYSTALLOGRAPHIC STRUCTURES OF THE SALTS [NMe4]3[Rh11(CO)23].Me2CO AND [NMe4]3[Rh11(CO)23].C6H5Me
1988-01-01 Fumagalli, Alessandro; Martinengo, S.; Ciani, G.; Sironi, A.; Heaton, B. T.
Bi-Co HETERONUCLEAR CARBONYL COMPOUNDS. SYNTHESIS OF THE ANION [Bi{Co(CO)4}4]- AND X-RAY CRYSTAL STRUCTURE OF ITS TETRAMETHYL AMMONIUM SALT
1988-01-01 Martinengo, S.; Fumagalli, Alessandro; Ciani, G.; Moret, M.
CRYSTAL AND MOLECULAR STRUCTURE OF THE NEUTRAL CLUSTER COMPOUND [Rh9(CO)19(NCMe){Cu(NCMe)2}] . C4H8O
1988-01-01 Ciani, G.; Moret, M.; Sironi, A.; Fumagalli, Alessandro; Martinengo, S.
MIXED-METAL CARBIDO CARBONYL CLUSTERS. PART 3. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [Rh6C(CO)15{Ag(NCMe)}2].0.5 MeOH, [Rh6C(CO)15{M(PPh3)}2] (M = Cu, Ag, or Au), AND OF THE ANION [Rh6C(CO)15{Au(PPh3)}]- AS ITS PPh4+ SALT
1988-01-01 Fumagalli, Alessandro; Martinengo, S.; Albano, V. G.; Braga, D.
Fe-promoted selective methanol synthesis in co hydrogenation catalyzed on SiO2-supported Ir4Fe and Pd6Fe6 bimetallic carbonyl cluster-derived catalysts
1989-01-01 Kimura, T.; Fukuoka, A.; Fumagalli, Alessandro; Ichikawa, M.
Synthesis and crystal and molecular structure of the neutral cluster compound [Rh9(CO)19(NCMe){Cu(NCMe)2}]
1989-01-01 Ciani, G.; Moret, M.; Fumagalli, Alessandro; Martinengo, S.
Synthesis and solution structure of the carbonyl cluster dianion [OsRh4(CO)9(µ2-CO)6]2-
1989-01-01 Fumagalli, Alessandro; Garlaschelli, L.; Della Pergola, R.
Mixed Pt-Rh carbonyl clusters. synthesis and chemical characterization of the [PtRh6(µ3-CO)3(µ-CO)5(CO)8]2- anion and x-ray crystal structure of its tetrapropylammonium salt
1989-01-01 Fumagalli, Alessandro; Martinengo, S.; Galli, D.; Albinati, A. Ganazzoli F.
Salts of mixed platinum-tetrarhodium cluster complexes
1989-01-01 Fumagalli, Alessandro; Martinengo, S.
72-76 VALENCE ELECTRON CLUSTERS; AN EXTENSION OF THE 16-18 ELECTRON RULE. SYNTHESIS, CRYSTAL STRUCTURE AND SOLUTION DYNAMICS OF THE TRIGONAL BIPYRAMIDAL PENTANUCLEAR CLUSTERS [PtIr4(CO)9(µ-CO)5]2- AND [PtIr4(CO)9(µ-CO)3]2-
1989-01-01 Fumagalli, Alessandro; DELLA PERGOLA, R.; Bonacina, F.; Garlaschelli, L.; Moret, M.; Sironi, A.
Bi-Co heteronuclear carbonyl compounds. Synthesis and X-Ray crystal structure of the cubane-like species [Co(CO)3(µ3-Bi)]4
1989-01-01 Ciani, G.; Moret, M.; Fumagalli, Alessandro; Martinengo, S.
MIXED-METAL CARBIDO CARBONYL CLUSTERS. PART 4. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [Rh6C(CO)13{Au2(PPh3)2}]
1989-01-01 Fumagalli, Alessandro; Martinengo, S.; Albano, V. G.; Braga, D.; Grepioni, F.
Synthesis and characterization of pentanuclear Fe–Ir carbonyl clusters. Solid-state structures of [N(PPh3)2]2[FeIr4(CO)15] and [PPh4][Fe2Ir3(CO)14]
1989-01-01 Della Pergola, R.; Garlaschelli, L.; Demartin, F.; Manassero, M.; Masciocchi, Norberto; Sansoni, M.; Fumagalli, Alessandro
New carbide clusters in the cobalt subgroup. Part 17. Preparation and structural characterization of the mixed-metal octahedral dianion [Co2Rh4C(CO)13]2– as its [PPh4]+ salt
1989-01-01 Albano, V. G.; Braga, D.; Grepioni, F.; Della Pergola, R.; Garlaschelli, L.; Fumagalli, Alessandro
Reactivity of Rh4(CO)12 with halides or pseudohalides; synthesis of the pentanuclear carbonyl clusters [Rh5(CO)14X]n- (X = Cl, Br, I, SCN, n = 2; X = PPh3, n = 1). Crystal structures of [N(PPh3)2][Rh5(µCO)6(CO)8(PPh3)] and [N(PPh3)2]2[Rh5(µCO)6(CO)8(SCN)]
1990-01-01 Fumagalli, Alessandro; Martinengo, S.; Galli, D.; Allevi, C.; Ciani, G.; Sironi, A.
Synthesis and characterization of heterometallic carbonyl cluster anions
1991-01-01 Fumagalli, Alessandro
Synthesis of two novel pentanuclear rhodium clusters bearing the alkyl-like ligands -CH2COOMe and -CH2CN. X-ray structure of [PPh4]2[Rh5(µ-CO)6(CO)8(CH2CN)]
1991-01-01 Ragaini, F.; Porta, F.; Fumagalli, Alessandro; Demartin, F.
[Rh(CO)4]-, [Rh5(CO)15]- and bimetallic clusters as catalysts for the carbonylation of nitrobenzene to methyl phenylcarbamate
1992-01-01 Ragaini, F.; Cenini, S.; Fumagalli, Alessandro; Crotti, C.
Synthesis and structural characterization of the nitrido-carbonyl cluster anion [Co7N(CO)15]2-, possessing a carbonyl stereochemistry different from that of its rhodium analogue
1992-01-01 Ciani, G.; Masciocchi, Norberto; Sironi, A.; Fumagalli, Alessandro; Martinengo, S.
MIXED RHODIUM-OSMIUM CARBONYL CLUSTERS. SYNTHESIS OF THE ANIONS [OsRh5(CO)16]- AND [OsRh3(CO)12]- AND CRYSTAL STRUCTURE OF THEIR [µ-NITRIDO-BIS(TRIPHENYLPHOSPHORUS)]+ SALTS
1992-01-01 Fumagalli, Alessandro; Martinengo, S.; Ciani, G.; Moret, M.; Sironi, A.
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