Using ab initio methods and natural bond orbital analysis, negative hyperconjugation is shown to govern L-lactate oxidation chemistry and may help to determine its enzymatic dehydrogenation mechanism.
Does negative hyperconjugation assist enzymatic dehydrogenations?
TABACCHI, GLORIA;GAMBA, ALDO;FOIS, ETTORE SILVESTRO
2007-01-01
Abstract
Using ab initio methods and natural bond orbital analysis, negative hyperconjugation is shown to govern L-lactate oxidation chemistry and may help to determine its enzymatic dehydrogenation mechanism.
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