A dinuclear iron-based catalytic system, bearing a new alkyl-bridged bis-[OSSO]-type ligand, for the coupling of CO2 with epoxides is reported. A turnover frequency up to 1680 h(-1) was recorded for propylene carbonate formation. A bimetallic cooperative reaction mechanism is proposed on the basis of kinetic analyses. These results give insights into the development of more efficient catalysts.
Dinuclear [OSSO]-Fe complexes for the reaction of CO2 with epoxides
Della Monica F;
2021-01-01
Abstract
A dinuclear iron-based catalytic system, bearing a new alkyl-bridged bis-[OSSO]-type ligand, for the coupling of CO2 with epoxides is reported. A turnover frequency up to 1680 h(-1) was recorded for propylene carbonate formation. A bimetallic cooperative reaction mechanism is proposed on the basis of kinetic analyses. These results give insights into the development of more efficient catalysts.
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