A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number of small molecules; the crystal structures of the anhydrous and fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, and reversible interconversion.
Sorption-desorption behavior of bispyrazolato-copper(II) 1D coordination polymers
GALLI, SIMONA;MASCIOCCHI, NORBERTO;
2005-01-01
Abstract
A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number of small molecules; the crystal structures of the anhydrous and fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, and reversible interconversion.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.