Two new 3D homoleptic binary imidazolates, Cd(im)2 and Hg(im)2 (Him = imidazole), as well as [Hg(im)]NO3, containing 1D polycations of [Hg(im)]n(n+) formulation, have been prepared and characterized by ab-initio XRPD methods.
Synthesis and ab-initio XRPD structure of group 12 imidazolato polymers
MASCIOCCHI, NORBERTO;ARDIZZOIA, GIAN ATTILIO;BRENNA, STEFANO;GALLI, SIMONA;MASPERO, ANGELO;
2003-01-01
Abstract
Two new 3D homoleptic binary imidazolates, Cd(im)2 and Hg(im)2 (Him = imidazole), as well as [Hg(im)]NO3, containing 1D polycations of [Hg(im)]n(n+) formulation, have been prepared and characterized by ab-initio XRPD methods.
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