Two highly porous coordination polymers, containing rare octanuclear hydroxo-nickel clusters and long bis-pyrazolyl spacers, are shown to possess, after mild thermal treatment, lattice cavities up to 72% of the total crystal volume.
Cubic octanuclear Ni(II) clusters in highly porous polypyrazolyl-based materials
MASCIOCCHI, NORBERTO;GALLI, SIMONA;MASPERO, ANGELO;PALMISANO, GIOVANNI;
2010-01-01
Abstract
Two highly porous coordination polymers, containing rare octanuclear hydroxo-nickel clusters and long bis-pyrazolyl spacers, are shown to possess, after mild thermal treatment, lattice cavities up to 72% of the total crystal volume.
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