The aminoarylation reaction of N -allylureas under oxidative palladium catalysis, in the absence of ligands and by using inexpensive H 2 O 2 as the sole oxidant, occurs in a chemo- and regioselective fashion. This intramolecular process takes place via a 5- exo -trig cyclization, and represents an easy approach to 4-arylmethyl imidazolidinones.

Chemo- and Regioselective Palladium(II)-Catalyzed Aminoarylation of N-Allylureas Providing 4-Arylmethyl Imidazolidinones

Foschi, Francesca;
2019-01-01

Abstract

The aminoarylation reaction of N -allylureas under oxidative palladium catalysis, in the absence of ligands and by using inexpensive H 2 O 2 as the sole oxidant, occurs in a chemo- and regioselective fashion. This intramolecular process takes place via a 5- exo -trig cyclization, and represents an easy approach to 4-arylmethyl imidazolidinones.
2019
https://www.thieme-connect.de/products/ejournals/journal/10.1055/s-00000084
palladium catalysis; aminoarylation; hydrogen peroxide; imidazolidinones; ureas; domino reaction
Giofrè, Sabrina; Beccalli, Egle; Foschi, Francesca; La Rosa, Concetta; Lo Presti, Leonardo; Christodoulou, Michail
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2086294
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