In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany

Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO6Ni2C2(Co)16]2−

Masciocchi N.;
1984-01-01

Abstract

In the title compound two C‐atoms are located in the cavity of a cluster. The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one. (Figure Presented.) Copyright © 1984 by Verlag Chemie, GmbH, Germany
1984
Arrigoni, A.; Ceriotti, A.; Pergola, R. D.; Longoni, G.; Manassero, M.; Masciocchi, N.; Sansoni, M.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2117672
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