A dinuclear iron-based catalytic system, bearing a new alkyl-bridged bis-[OSSO]-type ligand, for the coupling of CO2with epoxides is reported. A turnover frequency up to 1680 h−1was recorded for propylene carbonate formation. A bimetallic cooperative reaction mechanism is proposed on the basis of kinetic analyses. These results give insights into the development of more efficient catalysts.

Dinuclear [OSSO]-Fe complexes for the reaction of CO2 with epoxides

Della Monica F.;
2021-01-01

Abstract

A dinuclear iron-based catalytic system, bearing a new alkyl-bridged bis-[OSSO]-type ligand, for the coupling of CO2with epoxides is reported. A turnover frequency up to 1680 h−1was recorded for propylene carbonate formation. A bimetallic cooperative reaction mechanism is proposed on the basis of kinetic analyses. These results give insights into the development of more efficient catalysts.
2021
2021
Paradiso, V.; Della Monica, F.; Lamparelli, D. H.; D'Aniello, S.; Rieger, B.; Capacchione, C.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2129318
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