An operationally mild, ruthenium-based photocatalytic protocol has been developed for the conversion of gamma-mono- and gamma,gamma-disubstituted allyl carbonates in the presence of Umemoto's reagent to afford substituted six-membered cyclic carbonates. Variation and diversification of the carbonate ring substitution provides access to new monomers useful in ring-opening polymerization leading to polycarbonates with potentially tailored properties, as illustrated by comparative experiments using monomers with different pi-stacking capabilities.

Photocatalytic synthesis of substituted cyclic carbonate monomers for ring-opening polymerization

Della Monica F;
2021-01-01

Abstract

An operationally mild, ruthenium-based photocatalytic protocol has been developed for the conversion of gamma-mono- and gamma,gamma-disubstituted allyl carbonates in the presence of Umemoto's reagent to afford substituted six-membered cyclic carbonates. Variation and diversification of the carbonate ring substitution provides access to new monomers useful in ring-opening polymerization leading to polycarbonates with potentially tailored properties, as illustrated by comparative experiments using monomers with different pi-stacking capabilities.
2021
2021
https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.202100654
Cyclic carbonates; Photocatalysis; Ring-opening polymerization; Ruthenium; Trifluoromethyl
Maquilon, C; Della Monica, F; Limburg, B; Kleij, Aw
File in questo prodotto:
File Dimensione Formato  
Adv Synth Catal - 2021 - Maquil n - Photocatalytic Synthesis of Substituted Cyclic Carbonate Monomers for Ring‐Opening.pdf

non disponibili

Tipologia: Versione Editoriale (PDF)
Licenza: Copyright dell'editore
Dimensione 5.76 MB
Formato Adobe PDF
5.76 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2129322
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 8
  • ???jsp.display-item.citation.isi??? 8
social impact