In this review, we discuss the use of titanium complexes bearing either bridged diphenolate or calix[n]arene (n = 4, 6, 8) ligation, in the formation of plastics from α-olefins or via the ring opening polymerization (ROP) of cyclic esters. The syntheses, molecular structures and catalytic behaviour of these systems are discussed, as well as where possible, the properties of the resultant polymers.
Use of titanium complexes bearing diphenolate or calix[n]arene ligands in α-olefin polymerization and the ROP of cyclic esters
Santoro O.Primo
;
2020-01-01
Abstract
In this review, we discuss the use of titanium complexes bearing either bridged diphenolate or calix[n]arene (n = 4, 6, 8) ligation, in the formation of plastics from α-olefins or via the ring opening polymerization (ROP) of cyclic esters. The syntheses, molecular structures and catalytic behaviour of these systems are discussed, as well as where possible, the properties of the resultant polymers.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
