Molecular hydrogen and its isotopologues are key systems to test quantum electrodynamics (QED) at molecular length scales, as their energy levels can be calculated with high accuracy[1]. Comparison of the theoretical values with highly accurate experimental determinations of transition frequencies allows one to test QED and theories beyond the standard model of particle physics[2]. Recent accurate measurements of rovibrational frequencies of HD and D2, covering mostly the second overtone band, have shown a systematic deviation between measured and calculated transition frequencies. Yet, available measurements on H2 are characterized by uncertainties one order of magnitude larger than theory.

Comb-calibrated Raman Spectroscopy of Molecular Hydrogen

Lamperti M.
;
Ronchetti D.;
2023-01-01

Abstract

Molecular hydrogen and its isotopologues are key systems to test quantum electrodynamics (QED) at molecular length scales, as their energy levels can be calculated with high accuracy[1]. Comparison of the theoretical values with highly accurate experimental determinations of transition frequencies allows one to test QED and theories beyond the standard model of particle physics[2]. Recent accurate measurements of rovibrational frequencies of HD and D2, covering mostly the second overtone band, have shown a systematic deviation between measured and calculated transition frequencies. Yet, available measurements on H2 are characterized by uncertainties one order of magnitude larger than theory.
2023
979-8-3503-4599-5
Lamperti, M.; Rutkowski, L.; Ronchetti, D.; Gatti, D.; Gotti, R.; Cerullo, G.; Thibault, F.; Jozwiak, H.; Wojtewicz, S.; Maslowski, P.; Wcislo, P.; Po...espandi
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2178773
 Attenzione

L'Ateneo sottopone a validazione solo i file PDF allegati

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 0
  • ???jsp.display-item.citation.isi??? ND
social impact