In this study, we report highly precise and accurate measurements of the P(5), P(6), and O(3) transitions of the 2-0 band of HD occurring at approximately 1.5 mu m. HD spectra were acquired in the pressure range of 100-900 Torr using a cavity ring-down spectrometer linked to an optical frequency comb. The line-shape analysis was performed using the Hartmann-Tran profile in the so-called beta -corrected version. For the P(5) transition, we improved the accuracy of previous line center frequency determinations by more than two orders of magnitude. Moreover, for the P(5) and P(6) line centers, the total standard uncertainty is below 3 MHz, similar to those provided by quantum electrodynamics predictions, making them useful for direct comparisons that might foster future improvements of the theoretical model.

High-precision HD spectroscopy near 1.53 μm

Lamperti M.
Ultimo
2024-01-01

Abstract

In this study, we report highly precise and accurate measurements of the P(5), P(6), and O(3) transitions of the 2-0 band of HD occurring at approximately 1.5 mu m. HD spectra were acquired in the pressure range of 100-900 Torr using a cavity ring-down spectrometer linked to an optical frequency comb. The line-shape analysis was performed using the Hartmann-Tran profile in the so-called beta -corrected version. For the P(5) transition, we improved the accuracy of previous line center frequency determinations by more than two orders of magnitude. Moreover, for the P(5) and P(6) line centers, the total standard uncertainty is below 3 MHz, similar to those provided by quantum electrodynamics predictions, making them useful for direct comparisons that might foster future improvements of the theoretical model.
2024
2024
precision molecular spectroscopy; HD spectroscopy; cavity ring-down spectroscopy; optical frequency comb; line position
Gotti, R.; Wójtewicz, S.; Marangoni, M.; Gatti, D.; Lamperti, M.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2186492
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