The structure hardly changes when the cluster [Ir14(CO)27]− (1) is reduced to the dianion or oxidized to the neutral compound. The 14 Jr atoms form a trigonal bipyramid, which contains an Jr atom at the center of every edge (see picture). The terminal CO ligands cover the metal framework completely. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
Structure and Electrochemical Behavior of the Paramagnetic Anion [Ir14(CO)27]−, Possessing a Trigonal Bipyramidal Arrangement of Metal Atoms
Masciocchi N.;
1993-01-01
Abstract
The structure hardly changes when the cluster [Ir14(CO)27]− (1) is reduced to the dianion or oxidized to the neutral compound. The 14 Jr atoms form a trigonal bipyramid, which contains an Jr atom at the center of every edge (see picture). The terminal CO ligands cover the metal framework completely. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
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