The yellow, microcrystalline compound [Cu(pymo)] (Hpymo=2- hydroxypyrimidine) has been characterized with the newly emerging technique of ab initio X-ray powder diffraction. A unique and unprecedented crystal phase containing cyclic oligomers and infinite helical polymers (see picture) of the same monomeric fragment is selectively formed upon reaction of [Cu(CH3CN)4][BF4] and Hpymo with NEt3.
The unique formation of a crystal phase containing cyclic oligomers and helical polymers of the same monomeric fragment
MASCIOCCHI, NORBERTO;ARDIZZOIA, GIAN ATTILIO;MASPERO, ANGELO;SIRONI, ANNALISA
1999-01-01
Abstract
The yellow, microcrystalline compound [Cu(pymo)] (Hpymo=2- hydroxypyrimidine) has been characterized with the newly emerging technique of ab initio X-ray powder diffraction. A unique and unprecedented crystal phase containing cyclic oligomers and infinite helical polymers (see picture) of the same monomeric fragment is selectively formed upon reaction of [Cu(CH3CN)4][BF4] and Hpymo with NEt3.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
