Two complementary Pd-catalyzed protocols enabling the γ-selective intermolecular allylic amination of but-3-enoic acid derivatives are reported. These transformations can be successfully achieved via either a direct Pd(II)-catalyzed protocol or by way of a one-pot Pd(II)/Pd(0)-catalyzed sequence, depending on the nature of the nitrogen nucleophile used.

Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives

DIAMANTE, DARIA;GABRIELI, SARA;BENINCORI, TIZIANA;BROGGINI, GIANLUIGI;
2016-01-01

Abstract

Two complementary Pd-catalyzed protocols enabling the γ-selective intermolecular allylic amination of but-3-enoic acid derivatives are reported. These transformations can be successfully achieved via either a direct Pd(II)-catalyzed protocol or by way of a one-pot Pd(II)/Pd(0)-catalyzed sequence, depending on the nature of the nitrogen nucleophile used.
http://www.thieme-connect.com/ejournals/toc/synthesis
allylic acyloxylation; allylic amination; but-3-enoic acid derivatives; C-H activation; catalysis; palladium; Catalysis; Organic Chemistry
Diamante, Daria; Gabrieli, Sara; Benincori, Tiziana; Broggini, Gianluigi; Oble, Julie; Poli, Giovanni
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2051543
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