The novel tridentate ligand 1,3,5-tris(4-cyano-phenoxymethyl)-2,4,6- trimethylbenzene (1) together with silver-(I) triflate has afforded the interesting coordination polymer [Ag(1)(CF3SO3)]·0. 5H2O, containing undulated (6,3) layers of hexagonal meshes, with alternating Ag and 1 triconnected centers, entangled into 2-fold parallely interpenetrated sheets, which, furthermore, are polycatenated to generate an unique three-dimensional array.
An Unusual Three-Dimensional Coordination Network Formed by Parallel Polycatenation of Two-Fold Interpenetrated (6,3) Layers Based on a Novel Three-Connecting Ligand
Banfi S.;Carlucci L.;Caruso E.;
2004-01-01
Abstract
The novel tridentate ligand 1,3,5-tris(4-cyano-phenoxymethyl)-2,4,6- trimethylbenzene (1) together with silver-(I) triflate has afforded the interesting coordination polymer [Ag(1)(CF3SO3)]·0. 5H2O, containing undulated (6,3) layers of hexagonal meshes, with alternating Ag and 1 triconnected centers, entangled into 2-fold parallely interpenetrated sheets, which, furthermore, are polycatenated to generate an unique three-dimensional array.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
