The novel tridentate ligand 1,3,5-tris(4-cyano-phenoxymethyl)-2,4,6- trimethylbenzene (1) together with silver-(I) triflate has afforded the interesting coordination polymer [Ag(1)(CF3SO3)]·0. 5H2O, containing undulated (6,3) layers of hexagonal meshes, with alternating Ag and 1 triconnected centers, entangled into 2-fold parallely interpenetrated sheets, which, furthermore, are polycatenated to generate an unique three-dimensional array.

An Unusual Three-Dimensional Coordination Network Formed by Parallel Polycatenation of Two-Fold Interpenetrated (6,3) Layers Based on a Novel Three-Connecting Ligand

Banfi S.;Carlucci L.;Caruso E.;
2004-01-01

Abstract

The novel tridentate ligand 1,3,5-tris(4-cyano-phenoxymethyl)-2,4,6- trimethylbenzene (1) together with silver-(I) triflate has afforded the interesting coordination polymer [Ag(1)(CF3SO3)]·0. 5H2O, containing undulated (6,3) layers of hexagonal meshes, with alternating Ag and 1 triconnected centers, entangled into 2-fold parallely interpenetrated sheets, which, furthermore, are polycatenated to generate an unique three-dimensional array.
2004
Banfi, S.; Carlucci, L.; Caruso, E.; Ciani, G.; Proserpio, D. M.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11383/2134988
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